This forum is aimed to provide help with NETMF related questions. I still did a google search and found this for you
http://www.vending.org/technical/MDB_3.0.pdfFrom the doc, it looks like the interface is not TTL nor RS232 but actually it uses an optically isolated interface. See section 4.4 "example schematic".
Would be fun to see some updates on your project once you have something